HOF-102
| 【Numbering】BK2021013009 | 【CAS】CAS | ||
| 【Item No.】BK2021012346 | 【specification】 | ||
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Other name: HOF-102
CAS: NA
Structure information
Unit molecular formula C60H34O8 Unit molecular weight 882.90716
Monomer structure 6,60,600,600 0-(Pyrene-1,3,6,8-tetrayl)tetrakis(2-naphthoic acid) / H4PTTNA (CAS: 2010983-66-9)
Pore size 3.0nm, 2.5nm; layer spacing 3.65-3.71nm pore volume 1.35 cm3/g
Specific surface BET specific surface 2500 m2/g
Analog structure
產品性狀
產品形貌 黃色粉末
Yellow Powder
粒徑
穩定性
1) HOF-14/HOF-102是最穩定的有機多孔材料之一
2) 空氣中持久穩定，水溶液甚至沸水中穩定，在酸性和堿性溶液（PH 1-14）中穩定
2) 高熱穩定性、熱分解溫度大于 400℃
保存和活化方法
1) 常溫或低溫條件下，干燥密封保存
2) 建議使用前120度（真空）活化6小時
其他特性
NA
應用領域
1) 穩定的骨架結構可儲氣材料和吸附材料
2) 2.5-3.1nm的較大孔徑可吸附一些較大的分子離子、藥物、酶和RNA等大分子，尤其適用于酶固定。
3) HOF-102 易于和紡織纖維復合，用于柔性器件和傳感器開發
表征圖譜
references
1) Ma, K.; Li, P.; Xin, J.; Chen, Y.; Chen, Z.; Goswami, S.; Liu, X.; Kato, S.; Chen, H.; Zhang, X .; Bai, J.; Wasson, Me.; Maldonado, R.; Snurr, R.; Farha; O.; Cell Reports Physical Science 2020, 1, 100024, DOI:10.1016/j.xcrp.2020.100024; Ultrastable Mesoporous Hydrogen -Bonded Or-ganic Frameworks Based Fiber Composites To-ward Mustard Gas Detoxification
2) Wang, B.; Lv, X.; Lv, J.; Ma, L.; Lin, R.; Cui, H.; Zhang, J.; Zhang, Z.; Xiang, S.; Chen, B .; Chem. Commun., 2020, 56, 66-69, DOI: 10.1039/c9cc07802a; A novel mesoporous hydrogen-bonded organic framework with high porosity and stability
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