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MIL-101(Cr)

MIL-101(Cr)

【Numbering】BK2021012322 【CAS】869288-09-5
【Item No.】 【specification】
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Material name: MIL-101(Cr)
Other name: NA
CAS: 869288-09-5
Structure information
Unit molecular formula C24O15FCr3.O Unit molecular weight 719.2339
Coordination metal Cr ligand Terephthalic acid (CAS: 100-21-0)
Pore size Window: 1.2-1.6nm; Pore size: 2.9-3.4nm Pore volume 2.0-2.4 cm3/g
Specific surface BET specific surface 2800-3200 m2/g

Analog structure

Product traits
Product appearance: grayish green powder
Particle size
500-800nm
stability
1) MIL-101(Cr) is very stable in the air and can be stored stably for several months. Thermal decomposition temperature>300℃.
2) Stable in aqueous solution, resistant to strong acids and weak bases PH 1-12
3) Tolerance to F ions
Preservation and activation methods
1) Store in a dry and airtight condition at room temperature or low temperature
2) It is recommended to activate the 85°C (vacuum) oven for 10 hours before use
Other features
This product can be prepared by two methods: hydrothermal method and dry method (grinding): hydrothermal method has better crystallinity; grinding method has slightly poor crystallinity but higher BET value
Application field
1) Gas storage materials and adsorption materials
Characterization map

references
1) G. Férey, C. Mellot-Draznieks, C. Serre, F. Millange, J. Dutour, S. Surblé, I. Margiolaki, Science 2005, 309(5743), 2040-2042, DOI: 10.1126/science. 1116275; A Chromium Terephthalate-Based Solid with Unusually Large Pore Volumes and Surface Area


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