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MIL-53(Cr)

MIL-53(Cr)

【Numbering】BK2021012321 【CAS】442912-79-0
【Item No.】 【specification】
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Material name: MIL-53(Cr)
Other name: NA
CAS: 442912-79-0
Structure information
Unit molecular formula C8H4O5Cr Unit molecular weight 232.11046
Coordination metal Cr ligand Terephthalic acid (CAS: 100-21-0)
Pore size After activation 8.6 × 8.6 Å or 9.4 × 11.4 Å Pore volume
Specific surface BET specific surface cannot be measured

Analog structure

Grey Green Powder
Particle size 300-600nm
stability
1) MIL-53(Cr) is stable in air, stable in aqueous solution and acidic conditions
2) High thermal stability, thermal decomposition temperature greater than 300℃
Preservation and activation methods
1) Store in a dry and airtight condition at room temperature or low temperature
2) It is recommended to activate the oven at 150 degrees (vacuum) for 3 hours before use
Other features
Fluorescence: NA
Application field
1) Gas (such as carbon dioxide) and pollutant adsorption
2) It has good catalytic performance as a Lewis acid catalyst
Characterization map

references
1) C. Serre, F. Millange, C. Thouvenot, M. Noguès, G. Marsolier, D. Louër, G. Férey, J. Am. Chem. Soc. 2002, 124, 13519–13526, DOI: 10.1021/ ja0276974; Very Large Breathing Effect in the First Nanoporous Chromium(III)-Based Solids: MIL-53 or CrIII(OH)·{O2C−C6H4−CO2}·{HO2C−C6H4−CO2H}x·H2Oy


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