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PCN-224(H)

PCN-224(H)

【Numbering】BK2021012211 【CAS】1476810-88-4
【Item No.】 【specification】
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Material name: PCN-224(H)
Other name: NA
CAS: 1476810-88-4
Structure information
Unit molecular formula C144H72N12O64Zr15+2 Unit molecular weight 4362.51448
Coordination metal Zr ligand Tetracarboxyphenyl porphyrin H2TCPP (CAS: 14609-54-2)
Pore diameter 1.9nm Pore volume 1.59 cm3/g
Specific surface BET specific surface 2600 m2/g
Analog structure

Product traits
Product appearance red brown powder
Reddish Brown Powder
Particle size
stability
1) Long-lasting stability in the air, stable in aqueous solution and acid-weak alkali solution (PH 0-11)
2) Thermal decomposition temperature is about >400℃
Preservation and activation methods
1) Store in a dry and airtight condition at room temperature or low temperature
2) It is recommended to activate the oven at 80 degrees (vacuum) for 12 hours before use
Other features
Fluorescence: excitation wavelength 430nm, emission wavelength 652nm, showing red light
Application field
1) PCN-224(Co) has high catalytic activity for CO2/propylene oxide coupling reaction
2) PCN-224 shows up to 8.25mmol/g adsorption capacity for C3H8 at room temperature and 100kPa
3) PCN-224 can image cells and can be used as a photosensitizer to treat tumors
4) PCN-224 can detect Hg ions and nitro compounds, and PCN-224 (Pt) can detect oxygen.
  Characterization map

References

1) D. Feng, W.-C. Chung, Z. Wei, Z.-Y. Gu, H.-L. Jiang, Y.-P. Chen, D. J. Darensbourg, and H.-C. Zhou, J. Am. Chem. Soc. 2013, 135, 17105-17110, DOI: 10.1021/ja408084j
2) J. Park, Q. Jiang, D. Feng, L. Mao, and H.-C. Zhou, J. Am. Chem. Soc. 2016, 138, 3518-3525, DOI: 10.1021/jacs.6b00007



Warm tips: Suzhou Beike nano products are only used for scientific research, not for human body,different batches of products have different specifications and performance

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